RGPV TET CHEMISTRY Syllabus | Download RGPV TET Engg CHEMISTRY Syllabus www.rgpv.ac.in - CETJob
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Structure: Quantum  theory:  principles  and  techniques;  applications  to  a  particle  in  a  box,
harmonic oscillator, rigid rotor and hydrogen atom; valence bond and molecular orbital theories,
Hückel  approximation;  approximate  techniques:  variation  and  perturbation;  symmetry,  point
groups; rotational, vibrational, electronic, NMR, and ESR spectroscopy
Equilibrium: Kinetic  theory  of  gases;  First  law  of  thermodynamics,  heat,  energy,  and  work;
second law of thermodynamics and entropy; third law and absolute entropy; free ener gy; partial
molar  quantities;  ideal  and  non-ideal  solutions;  phase  transformation:  phase  rule  and  phase
diagrams  –  one, two, and three component systems; activity, activity coefficient, fugacity, and
fugacity coefficient; chemical equilibrium, response of  chemical equilibrium to temperature and
pressure; colligative properties; Debye-Hückel theory; thermodynamics of electrochemical cells;
standard  electrode  potentials:  applications  –  corrosion  and  energy  conversion;  molecular
partition function (translational, rotational, vibrational, and electronic).

Kinetics: Rates  of  chemical  reactions,  temperature  dependence  of  chemical  reactions;
elementary, consecutive, and parallel reactions; steady state approximation; theories of reaction
rates  –  collision  and  transition  state  theory,  relaxation  kinetics,  kinetics  of  photochemical
reactions  and  free  radical  polymerization,  homogeneous  catalysis,  adsorption  isotherms  and
heterogeneous catalysis.
Main group elements: General characteristics, allotropes, structure and reactions of simple and
industrially  important  compounds:  boranes,  carboranes,  silicones,  silicates,  boron  nitride,
borazines and phosphazenes. Hydrides, oxides and oxoacids of pnictogens (N, P), chalcogens (S,
Se & Te) and halogens, xenon compounds, pseudo halogens and interhalogen compounds.Shapes
of molecules and hard-  soft acid base concept. Structure and Bonding (VBT) of B, Al, Si, N, P,
S,  Cl  compounds.  Allotropes  of  carbon:  graphite,  diamond,  C60.  Synthesis  and  reactivity  of
inorganic polymers of Si and P.
Transition Elements: General characteristics of d and f block elements; coordination chemistry:
structure  and  isomerism,  stability,  theories  of  metal-  ligand  bonding  (CFT  and  LFT),
mechanisms of substitution and electron transfer reactions of coordination complexes. Electronic
spectra and magnetic properties of transition metal complexes, lanthanides and actinides. Metal
carbonyls, metal- metal bonds and metal atom clusters, metallocenes; transition metal complexes
with  bonds  to  hydrogen,  alkyls,  alkenes  and  arenes;  metal  carbenes;  use  of  organometallic
compounds as catalysts in organic synthesis. Bioinorganic chemistry of Na, K. Mg, Ca, Fe, Co,
Zn, Cu andMo.
Solids: Crystal systems and lattices, miller planes, crystal packing,  crystal defects; Bragg’s Law,
ionic  crystals,  band  theory,  metals  and  semiconductors,  Different  structures  of  AX,  AX
2ABX3 compounds, spinels.
Instrumental  methods  of  analysis:  Atomic  absorption  and  emission  spectroscopy  including
ICP-AES,  UV-  visible  spectrophotometry,  NMR,  mass,  Mossbauer  spectroscopy  (Fe  and  Sn),
ESR  spectroscopy,  chromatography  including  GC  and  HPLC  and  electro-analytical  methods
(Coulometry, cyclic voltammetry, polarography – amperometry, and ion selective electrodes).
Stereochemistry: Chirality of organic molecules with or without chiral centres. Specification of
configuration  in  compounds  having  one  or  more  stereogeniccentres.  Enantiotopic  and
diastereotopic  atoms,  groups  and  faces.  Stereoselective  and  stereospecific  synthesis.
Conformational  analysis  of  acyclic  and  cyclic  compounds.  Geometrical  isomerism.
Configurational and conformational effects on reactivity and selectivity/specificity.
Reaction  mechanism:  Methods  of  determining  reaction  mechanisms.  Nucleophilic  and
electrophilic  substitutions  and  additions  to  multiple  bonds.  Elimination  reactions.  Reactive
intermediates-  carbocations,  carbanions,  carbenes,  nitrenes,  arynes,  free  radicals.  Molecular
rearrangements involving electron deficient atoms.
Organic  synthesis:  Synthesis,  reactions,  mechanisms  and  selectivity  involving  the  followingalkenes,  alkynes,  arenes,  alcohols,  phenols,  aldehydes,  ketones,  carboxylic  acids  and  their
derivatives, halides, nitro compounds and amines. Use of compounds of Mg, Li, Cu, B  and Si in
organic  synthesis.  Concepts  in  multistep  synthesis-  retrosynthetic  analysis,  disconnections,
synthons, synthetic equivalents, reactivity umpolung, selectivity, protection and deprotection of
functional groups.
Pericyclic reactions: Electrocyclic,  cycloaddition and sigmatropic reactions. Orbital correlation,
FMO and PMO treatments.
Photochemistry: Basic principles. Photochemistry of alkenes, carbonyl compounds, and arenes.
Photooxidation and photoreduction. Di-π- methane rearrangement, Barton reaction.
Heterocyclic  compounds:  Structure,  preparation,  properties  and  reactions  of  furan,  pyrrole,
thiophene, pyridine, indole and their derivatives.
Biomolecules: Structure, properties and reactions of mono-  and di-saccharides, physicochemical
properties of  amino acids, chemical synthesis of peptides, structural features of proteins, nucleic
acids, steroids, terpenoids, carotenoids, and alkaloids.
Spectroscopy:  Principles  and  applications  of  UV-visible,  IR,  NMR  and  Mass  spectrometry  in
the determination of structures of organic molecules

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